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To ensure that the CTRL+B character (STX) is properly transmitted when using USB scanners in conjunction with Terminal Services, ensure that the option under Local Resources for Windows Key Combinations for the RDP Client is set to: “On the local computer.” This will ensure that all keyboard input is transmitted correctly to the Terminal Server session
Also see article: http://wiki.wws5.com/doku.php?id=faq:using_barcode_scanners_with_windows_terminal_services
See screen-shots below: